Anhydrous Borax in Fly Ash–Slag Geopolymer Concrete: Evidence and a Research Framework

Authors

  • Jiayu Xiao Central South University of Forestry and Technology, Changsha, China Author

DOI:

https://doi.org/10.63313/FE.9019

Keywords:

Anhydrous Borax, Fly Ash–Slag Geopolymer Concrete, Setting Control, Workability Retention, Research Framework

Abstract

Rapid setting and loss of workability can restrict the use of fly ash–slag geopolymer concrete, particularly when slag is introduced to support strength development under ambient conditions. This narrative review examines the evidence for borate-mediated reaction control and develops a research framework for externally added anhydrous borax. Published studies are compared by precursor composition, activation route, borax hydration state, and the relationship between fresh and hardened properties. The synthesis identifies a recurring possibility of delayed setting, but the associated strength response varies with formulation and age. Evidence obtained with hydrated borax, elevated-temperature fly ash systems, or combined admixtures does not establish a transferable dosage for anhydrous borax in concrete. A staged framework is therefore proposed in which matched paste and mortar screening precede verification across concrete formulations with different target strengths. The base activator and water contents remain fixed, while borax-derived sodium is reported separately. Dosage selection combines a usable placement window, flow retention, stability, and strength requirements; full compressive responses and complementary microstructural measurements then test the consequences of the selected treatment. The framework distinguishes observed retardation from proposed surface inhibition and network modification mechanisms. Its contribution is a traceable route for evaluating a formulation-specific performance window, without presuming an optimum dosage or presenting planned experiments as completed results.

References

[1] Nath, P. and Sarker, P.K. (2014) Effect of GGBFS on Setting, Workability and Early Strength Properties of Fly Ash Geopolymer Concrete Cured in Ambient Condition. Construction and Building Materials, 66, 163–171. https://doi.org/10.1016/j.conbuildmat.2014.05.080

[2] Ben Haha, M., Le Saout, G., Winnefeld, F. and Lothenbach, B. (2011) Influence of Activator Type on Hydration Kinetics, Hydrate Assemblage and Microstructural Development of Alkali Activated Blast-Furnace Slags. Cement and Concrete Research, 41(3), 301–310. https://doi.org/10.1016/j.cemconres.2010.11.016

[3] Ismail, I., Bernal, S.A., Provis, J.L., San Nicolas, R., Hamdan, S. and van Deventer, J.S.J. (2014) Modification of Phase Evolution in Alkali-Activated Blast Furnace Slag by the Incorporation of Fly Ash. Cement and Concrete Composites, 45, 125–135. https://doi.org/10.1016/j.cemconcomp.2013.09.006

[4] Garcia-Lodeiro, I., Palomo, A., Fernández-Jiménez, A. and Macphee, D.E. (2011) Compatibility Studies between N-A-S-H and C-A-S-H Gels. Study in the Ternary Diagram Na₂O–CaO–Al₂O₃–SiO₂–H₂O. Cement and Concrete Research, 41(9), 923–931. https://doi.org/10.1016/j.cemconres.2011.05.006

[5] Liu, H., Sanjayan, J.G. and Bu, Y. (2017) The Application of Sodium Hydroxide and Anhydrous Borax as Composite Activator of Class F Fly Ash for Extending Setting Time. Fuel, 206, 534–540. https://doi.org/10.1016/j.fuel.2017.06.049

[6] Li, P., Chen, D., Jia, Z., Li, Y., Li, S. and Yu, B. (2023) Effects of Borax, Sucrose, and Citric Acid on the Setting Time and Mechanical Properties of Alkali-Activated Slag. Materials, 16(8), 3010. https://doi.org/10.3390/ma16083010

[7] Yousefi Oderji, S., Chen, B. and Mohseni, E. (2023) The Efficiency of Borax as an Additive on Properties of One-Part Fly Ash/Slag-Based Alkali-Activated Materials. European Journal of Environmental and Civil Engineering, 27(14), 4237–4249. https://doi.org/10.1080/19648189.2023.2182367

[8] Hanani, E., Satyarno, I. and Sulistyo, D. (2024) Mix Design of Ambient Cured Geopolymer Concrete with Fly Ash, GGBFS, and Borax. INERSIA: Informasi dan Ekspose Hasil Riset Teknik Sipil dan Arsitektur, 20(2), 265–276. https://doi.org/10.21831/inersia.v20i2.74464

[9] Tran, M.V., Vu, T.H. and Nguyen, T.H.Y. (2023) Simplified Assessment for One-Part 3D-Printable Geopolymer Concrete Based on Slump and Slump Flow Measurements. Case Studies in Construction Materials, 18, e01889. https://doi.org/10.1016/j.cscm.2023.e01889

[10] Yu, H., Zhou, Y., Xia, W. and Xu, T. (2025) Synergistic Mechanism and Performance Enhancement of Fly Ash-Slag-Based Geopolymer with Sodium Tetraborate and Aminopropyltriethoxysilane for Retardation. Construction and Building Materials, 487, 142055. https://doi.org/10.1016/j.conbuildmat.2025.142055

[11] Wang, J., Han, L., Liu, Z. and Wang, D. (2020) Setting Controlling of Lithium Slag-Based Geopolymer by Activator and Sodium Tetraborate as a Retarder and Its Effects on Mortar Properties. Cement and Concrete Composites, 110, 103598. https://doi.org/10.1016/j.cemconcomp.2020.103598

[12] Noushini, A., Aslani, F., Castel, A., Gilbert, R.I., Uy, B. and Foster, S. (2016) Compressive Stress-Strain Model for Low-Calcium Fly Ash-Based Geopolymer and Heat-Cured Portland Cement Concrete. Cement and Concrete Composites, 73, 136–146. https://doi.org/10.1016/j.cemconcomp.2016.07.004

[13] Zhang, Z., Zhu, Y., Zhu, H., Zhang, Y., Provis, J.L. and Wang, H. (2019) Effect of Drying Procedures on Pore Structure and Phase Evolution of Alkali-Activated Cements. Cement and Concrete Composites, 96, 194–203. https://doi.org/10.1016/j.cemconcomp.2018.12.003

Downloads

Published

2026-09-15

Issue

Section

Articles

How to Cite

Anhydrous Borax in Fly Ash–Slag Geopolymer Concrete: Evidence and a Research Framework. (2026). Frontiers in Engineering, 2(1), 10–20. https://doi.org/10.63313/FE.9019